Materials>>Silicon window

Silicon windows, Silicon lenses

Alkor Technologies produces wide range of Silicon optical components according to customer's specification:

The largest dimensions of Silicon optics - 150mm diameter.
Silicon lenses - Dia 3mm Silicon lenses for IR LEDs, Diameter 3mm

Optical grade Silicon is normally specified with a resistivity of 10 to 40 ohm-cm which is higher than most semiconductor applications. The usual Silicon material, unless otherwise specified is CZ, Czochralski Grade which has a Si-O absorption band at 9μm and so not important if the windows are used in the 3 to 5μm thermal band. Where required FZ, Float Zone material can be supplied which does not have this absorption.

Very high resistivity material can be supplied on special order, particularly for TeraHertz applications.

Silicon is used for windows and lenses in the 2-7µm range, ideal choice for IR LED lenses. The refractive index is near 3.4 throughout the range. Silicon high thermal conductivity and low weight are attractive features in IR or FTIR applications. Silicon is also used as a high reflectivity mirror for lasers.

Si transmission

Different types of Silicon are available:

  • Czochralski standard low-cost n-type (resistivity >10 Ohm*cm) or p-type (>20 Ohm*cm)
  • high resistivity Float-Zone Silicon with resistivity >1000 Ohm*cm.

Due to the strong absorbtion at 9mkm, Silicon is not suitable for use with CO2 lasers as a transmitting optic but is widely used for CO2 mirrors. The density of Silicon is only half that of Germanium and Zinc Selenide.

Silicon properties
Chemical Formula Si
Molecular Weight 28.09
Crystal Class Cubic
Lattice Constant, Å 5.43
Density, g/cm3 at 293 K 2.329
Dielectric Constant for 9.37 x 109 Hz 13
Melting Point, K 1690
Thermal Conductivity, W/(m K)
at 125 K
at 313 K
at 400 K

598.6
163
105.1
Thermal Expansion, 1/K
at 75 K
at 293 K
at 1400 K

-0.5 x 10-6
2.6 x 10-6
4.6 x 10-6
Specific Heat, cal/(g K)
at 298 K
at 1800 K

0.18
0.253
Debye Temperature, K 640
Bandgap, eV 1.1
Solubility in water None
Knoop Hardness, kg/mm2 1100
Mohs Hardness 7
Young's Modulus, GPa 130.91
Shear Modulus, GPa 79.92
Bulk Modulus, GPa 101.97
Poisson's Ratio 0.28
Silicon index of refraction
Wavelength, µm 1.40 1.50 1.66 1.82 2.05 2.50 3.50-5.00 6.00-25.00
Refractive Index 3.49 3.48 3.47 3.46 3.45 3.44 3.43 3.42